‘不 + adjective’ can be in a negative imperative sentence, but not in a positive one.
别不识相,他不欢迎咱们,咱们走吧!
Bié bú shí xiàng ,tā bú huān yíng zán men ,zán men zǒu ba !
Don’t be clueless. We are not welcome here. Let’s go.
别不好意思,上来表演一下吧!
Bié bú hǎo yì sī ,shàng lái biǎo yǎn yī xià ba !
Don’t be shy. Come up here and perform (a song, a dance, etc.)!
[1] Yip, P. C., Rimmington, D., Xiaoming, Z., & Henson, R. (2009). Basic Chinese: a grammar and workbook. Taylor & Francis.